MATERIAL SAFETY DATA
SHEET
|
EVERGREEN OIL, INC
6880 SMITH AVE
NEWARK, CA. 94560
(510) 795-4400 |
FURTHER INFO: (510) 795-4400
EMERGENCY - TRANSPORTATION: CHEMTREC (800) 424-9300
EMERGENCY - HEALTH: 911 |
|
SUBSTANCE
IDENTIFICATION
|
| IDENTITY: |
ASPHALT FLUX |
| CAS NUMBER: |
129893-17-0 |
| SYNONYM / TRADE NAMES: |
ASPHALT EXTENDER, LUWA BOTTOMS, VACUUM TOWER BOTTOMS |
| FAMILY / CHEMICAL NAME: |
HYDROCARBON, PETROLEUM; RE-REFINED, LUBRICATING OIL
RESIDUES |
| NFPF RATINGS (SCALE 0-4): |
O-HEALTH, 1-FIRE, 0-REACTIVITY |
| MSDS FORM NO.: |
ASPHMSDS.DOC992 |
|
| HAZARDOUS
INGREDIENTS |
| THIS PRODUCT FITS THE ACGIH DEFINITION FOR USED OIL
VACUUM RESIDUES. |
| PERCENT: 100 WT% |
CAS NO.: 129893-17-0 |
| NOTE: HYDROGEN SULFIDE CONCENTRATION DISSOLVED IN
ASPHALT IS LESS THAN 0.1 WT%, BUT MAY GIVE RISE TO VAPOR
CONCENTRATIONS IN STORAGE TANKS IN EXCESS OF THE OSHA PEL OR ACGIH
TLV LIMITS. |
| PERCENT: <0.1 WT% |
CAS NO.: 7783-06-4 |
| EXPOSURE LIMITS IN AIR |
| |
OIL RESIDUE |
HYDROGEN SULFIDE |
|
| OSHA PEL TWA |
NONE ESTABLISHED |
10 PPM |
| OSHA PEL STEL |
NONE ESTABLISHED |
15 PPM |
|
| ACGIH TLV TWA |
5 MG/M? (FUMES) |
10 PPM |
| ACGIH TLV STEL |
NONE ESTABLISHED |
15 PPM |
|
| CAL OSHA PEL |
NONE ESTABLISHED |
10 PPM |
| CAL OSHA STEL |
NONE ESTABLISHED |
15 PPM |
| CAL OSHA CEILING |
NONE ESTABLISHED |
50 PPM |
|
|
| PHYSICAL
PROPERTIES |
| VAPOR DENSITY: >1 ( AIR = 1) |
MELTING PT.: NOT APPLICABLE |
| SPECIFIC GRAVITY: : 0.98 @60 °F |
BOILING POINT: ABOVE 475 °F (246 °C) |
| SOLUBILITY IN WATER: INSOLUBLE |
EVAPORATION RATE: 0.001 (ETHER=1) |
| % VOLATILE: NEGLIGIBLE |
VAPOR PRESSURE: <0.2 MM HG @ 80 °C |
| DENSITY: 8.2 LBS/GAL |
API GRAVITY: 14 TO 17 °API @ 60 °F |
| COEFFICIENT OF WATER/OIL DIST.: LESS THAN 1 |
POUR PT: 40°F (4°C) |
| 'MOLECULAR WEIGHT: >525 |
| HOW TO DETECT THIS SUBSTANCE : |
BLACK, VISCOUS, SEMI-SOLID, WITH A STICKY DISPOSITION AND
BURNT, ASPHALTISH ODOR. SLOW TO POUR, AND FLOATS ON WATER. |
|
FIRE AND EXPLOSION
DATA
|
| FLASH PT: >550 °F (287 °C) COC |
AUTOIGNITION TEMP: 640 °F (338 °C) |
| LOWER FLAMMABLE LIMIT: 1 VOL. % |
UPPER FLAMMABLE LIMIT: 5.5 VOL. %
(BASED ON DECANE) |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, DRY
CHEMICAL. NOTE: DO NOT USE WATER ON MATERIAL THAT IS HOTTER THAN
200 °F AS AN EXPLOSION MAY RESULT.
|
HAZARDOUS COMBUSTION
PRODUCTS
|
THERMAL DECOMPOSITION AND BURNING MAY PRODUCE THE
FOLLOWING HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE,
HYDROGEN SULFIDE, NITROGEN OXIDES, AND OTHER TOXIC MATERIALS.
|
|
| UNUSUAL FIRE AND EXPLOSION
DATA |
MOVE CONTAINER FORM FIRE AREA IF YOU
CAN DO SO WITHOUT RISK. AVOID ANY CONTACT WITH WATER WHEN MATERIAL
IS ABOVE 200 oF. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT
ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM
ENDS OF TANKS AND DRUMS - HEATED CONTAINERS MAY RUPTURE, EXPLODE OR
BE THROWN INTO THE AIR. HEATED VAPORS MAY BE SENSITIVE TO STATIC
DISCHARGE - RESULTING IN FIRE OR EXPLOSION.
|
FIRE FIGHTING PROCEDURES
CAUTION: WATER OR FOAM MAY CAUSE FROTHING. WITHDRAW IMMEDIATELY IN
CASE OF RISING SOUND FROM VENTING SAFETY DEVICE OR DISCOLORATION OF
TANK DUE TO FIRE. KEEP STORAGE CONTAINERS COOL WITH WATER SPRAY.
USE SELF-CONTAINED BREATHING APPARATUS (SCBA). |
| NFPA 704 RATING (0=LEAST, 4=EXTREME) : |
HEALTH=0, FIRE=1, REACTIVITY=0; |
|
| HEALTH HAZARD
INFORMATION |
| SYMPTOMS OF EXPOSURE |
|
ACUTE: |
| INHALED: |
HIGH CONCENTRATIONS OF VAPOR MIST MAY BE IRRITATING TO THE
RESPIRATORY TRACT, INCLUDING NOSE AND THROAT. MAY CAUSE DIFFICULTY
BREATHING. INHALATION OF HYDROGEN SULFIDE RELEASED FROM HOT PRODUCT
IN ENCLOSED AREAS MAY PRODUCE UNCONSCIOUSNESS, CONVULSIONS,
RESPIRATORY PARALYSIS, COMA AND DEATH.
|
| SKIN: |
THIS MATERIAL MAY CAUSE SKIN IRRITATION. PROLONGED OR REPEATED
CONTACT MAY CAUSE REDNESS, BURNING, AND DERMATITIS. CONTACT WITH
HOT MATERIAL MAY CAUSE THERMAL BURNS.
|
| EYES: |
CONTACT MAY CAUSE SLIGHT TO MODERATE IRRITATION, INCLUDING
BURNING, TEARING, AND REDNESS. CONTACT WITH HOT MATERIAL MAY CAUSE
THERMAL BURNS.
|
| SWALLOWING
(INGESTION): |
MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT, NAUSEA AND
VOMITING.
|
|
CHRONIC |
PROLONGED AND/OR REPEATED SKIN CONTACT MAY CAUSE
DRYING AND CRACKING OR DERMATITIS. PROLONGED OR REPEATED SKIN
EXPOSURE TO HOT VAPORS MAY CAUSE PHOTO SENSITIZATION AND MELANOSIS.
EXCESS EYE EXPOSURE TO HOT VAPORS MAY CAUSE CONJUNCTIVITIS.
|
| MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE |
CONTACT WITH SKIN MAY AGGRAVATE PRE-EXISTING
DERMATITIS. INDIVIDUALS WITH PRE-EXISTING LUNG OR CENTRAL NERVOUS
SYSTEM DISORDERS MAY HAVE INCREASED SUSCEPTIBILITY TO THE EFFECTS
OF EXPOSURE.
|
|
CARCINOGENICITY |
| NO INGREDIENTS OF THIS PRODUCT, PRESENT AT EQUAL TO
OR GREATER THAN 0.1% OF THE PRODUCT, ARE LISTED BY OSHA, NTP OR
IARC AS SUSPECTED CARCINOGENS. |
|
| EMERGENCY AND FIRST AID
PROCEDURES |
INHALED (BREATHING):
REMOVE TO FRESH AIR IMMEDIATELY. IF THERE IS DIFFICULTY
BREATHING OR IF BREATHING HAS STOPPED, OXYGEN OR ARTIFICIAL
RESPIRATION SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. DO NOT
LEAVE VICTIM UNATTENDED. SEEK IMMEDIATE MEDICAL ATTENTION IF
NECESSARY.
|
SKIN:
REMOVE CONTAMINATED CLOTHING AND SHOES. DO NOT USE
GASOLINE, THINNERS OR SOLVENTS TO REMOVE PRODUCT FROM SKIN.
IMMEDIATELY COOL AFFECTED AREA BY FLUSHING OR IMMERSING IN WATER
UNTIL MATERIAL SOLIDIFIES. DO NOT REMOVE SOLIDIFIED MATERIALS AS
THIS MIGHT CAUSE TEARING OF THE SKIN. COVER AREA WITH STERILE DRY
DRESSING, AND CONSULT A PHYSICIAN.
|
EYES:
DIRECT CONTACT, FLUSH EYES WITH WATER FOR 15 MINUTES
LIFTING UPPER AND LOWER LIDS OCCASIONALLY. CONSULT PHYSICIAN IF
IRRITATION OR PAIN PERSISTS.
|
SWALLOWING (INGESTION):
DO NOT INDUCE VOMITING, BECAUSE MATERIAL CAN ENTER THE
LUNGS AND CAUSE SEVERE DAMAGE. DRINK 4 TO 8 OUNCES OF WATER AND
SEEK IMMEDIATE MEDICAL ATTENTION. IF VOMITING OCCURS, OR IF
COMATOSE OR LETHARGIC, PLACE ON THE LEFT SIDE WITH THE HEAD DOWN -
SEEK IMMEDIATE MEDICAL ATTENTION.
|
NOTE TO PHYSICIAN:
ADMINISTRATION OF GASTRIC LAVAGE, IF WARRANTED, SHOULD
BE PERFORMED BY QUALIFIED MEDICAL PERSONNEL.
|
|
| REACTIVITY
DATA |
| STABILITY: |
STABLE, NOT REACTIVE WITH WATER. |
| INCOMPATIBILITY: |
MAY REACT WITH STRONG OXIDIZING AGENTS, SUCH AS; CHLORATES,
NITRATES AND PEROXIDES. AVOID SPARKS AND FLAMES. AVOID CONTACT WITH
WATER OR OTHER LIQUIDS WHEN MATERIAL IS HOT. |
| HAZARDOUS POLYMERIZATION: |
NOT KNOWN TO OCCUR UNDER NORMAL TEMPERATURES AND
PRESSURES. |
| HAZARDOUS DECOMPOSITION: |
NO DECOMPOSITION PRODUCTS UNDER NORMAL PRODUCT CONDITIONS |
| SPECIAL PRECAUTIONS: |
| READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL.
DO NO WELD, HEAT OR DRILL CONTAINER. RESIDUE MAY IGNITE WITH
EXPLOSIVE VIOLENCE IF HEATED SUFFICIENTLY. CAUTION..DO NOT USE
PRESSURE TO EMPTY DRUM OR EXPLOSION MAY RESULT. DO NOT CONTACT WITH
WATER WHEN MATERIAL IS HOT (ABOVE 200 °F) |
|
| SPILL, LEAK, AND DISPOSAL
PROCEDURES |
| SPILL PROCEDURE |
| REMOVE ALL IGNITION SOURCES, AND AVOID BREATHING VAPORS.
VENTILATE AREA IF CONFINED. CONTAIN BY DIKING AROUND OIL WITH A
SUITABLE MATERIAL. IF NOT, ABSORB SPILLED LIQUID IN SAND OR INERT
ABSORBENT. CONTAIN AWAY FROM SURFACE WATERS AND SEWERS. SHOVEL INTO
CLOSABLE CONTAINER FOR DISPOSAL. CONTACT THE COAST GUARD NATIONAL
RESPONSE CENTER (800) 424-8802 IF A SPILL OF ANY AMOUNT IS MADE
INTO OR UPON U.S. NAVIGABLE WATERS, THE CONTIGUOUS ZONE, OR
ADJOINING SHORELINES. |
| WASTE DISPOSAL METHODS |
| DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, COUNTY, AND LOCAL
REGULATIONS. CONTACT EVERGREEN OIL REGARDING RECYCLING OR
DISPOSAL. |
|
SPECIAL HANDLING
INFORMATION
VENTILATION AND HANDLING PRECAUTIONS |
| KEEP AWAY FORM HEAT, SPARKS AND FLAMES. AVOID CONTACT WITH EYES
AND SKIN, AND AVOID BREATHING VAPORS OR MISTS. AVOID GENERATING OIL
MISTS. |
| RESPIRATORY PROTECTION |
| WHEN AIRBORNE CONCENTRATIONS EXCEED RECOMMENDED EXPOSURE
LIMITS, A MSHA/NIOSH APPROVED RESPIRATORY PROTECTIVE EQUIPMENT
SHOULD BE WORN, SUCH AS AN ORGANIC VAPOR AND HYDROGEN SULFIDE
FILTERED REPIRATOR. A SELF-CONTAINED BREATHING APPARATUS (SCBA) IS
REQUIRED FOR FIRE EMERGENCIES. |
| EYE PROTECTION |
| WHERE THERE IS A LIKELIHOOD OF A SPILL OR SPLASH, WEAR CHEMICAL
GOGGLES AND FACE SHIELD. CONTACT LENSES SHOULD NOT BE WORN. |
| HAND PROTECTION |
| USE NEOPRENE, NITRILE RUBBER, OR EQUIVALENT GLOVES TO PREVENT
CONTACT WITH THE SKIN. FOR DIRECT CONTACT WITH HOT MATERIAL, USE
COMBINATION TEMPERATURE RESISTANT AND CHEMICAL PROTECTIVE
GLOVES. |
| OTHER PROTECTIVE CLOTHING |
| WEAR APPROPRIATE BOOTS, COVERALLS OR OTHER PROTECTIVE CLOTHING
WHERE SPILLS AND SPLASHES ARE POSSIBLE. A SOURCE OF CLEAN WATER
SHOULD BE AVAILABLE IN WORK AREAS FOR FLUSHING THE EYES AND SKIN IF
NECESSARY. |
| STORAGE |
| STORE IN A COOL , DRY LOCATION. KEEP AWAY FROM INCOMPATIBLE
MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. EMPTY PRODUCT CONTAINERS
MAY CONTAIN PRODUCT RESIDUE. DO NOT PRESSURIZE, CUT, HEAT, WELD, OR
EXPOSE CONTAINERS TO FLAME OR OTHER SOURCES OF IGNITION. |
|
TRANSPORTATION AND OTHER
REGULATORY INFORMATION
|
DOT INFORMATION IS APPLICABLE WHEN TRANSPORTATION
TEMPERATURE IS GREATER THAN 212°F (100°C). OTHERWISE, NOT
REGULATED.
|
| DOT SHIPPING NAME: |
ELEVATED TEMPERATURE MATERIAL, LIQUID, N.O.S. (FLUX) |
| DOT ID NUMBER: |
NA9259, PG III |
| DOT CLASS: |
CLASS 9 |
| TSCA: |
COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA
INVENTORY
|
| SARA TITLE III: |
PRODUCT DOES NOT CONTAIN TOXIC CHEMICALS SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND RE AUTHORIZATION ACT OF 1986 AND 40 CFR
PART 372.
|
| SECTION 311 CATEGORIES: |
IMMEDIATE (ACUTE) HEALTH EFFECT; |
YES |
| |
DELAYED (CHRONIC) HEALTH EFFECTS; |
NO |
| |
FIRE HAZARD; |
NO |
| |
SUDDEN RELEASE OF PRESSURE HAZARD; |
NO |
| |
REACTIVITY HAZARD; |
NO |
|
|
THE INFORMATION CONTAINED IN THIS MSDS IS BELIEVED TO BE ACCURATE,
AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO
EVERGREEN OIL. EVERGREEN OIL MAKES NO WARRANTY OF MERCHANTABILITY
OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH
INFORMATION, AND ASSUMES NO LIABILITY RESULTING FROM USE OF THIS
INFORMATION. USERS OF THIS PRODUCT SHOULD MAKE THEIR OWN EVALUATION
TO DETERMINE THE SUITABILITY OF THE PRODUCT FOR THEIR PARTICULAR
PURPOSES, AND SHOULD ESTABLISH SAFE HANDLING PROCEDURES. |
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PREPARED BY: LAB MSDS COORDINATOR
REVISED: REVISED: JUNE 30,
2003 SUPERSEDES:
July 22, 1995 |
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